CAS 76189-56-5

Products Name

(S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl

CAS 76189-56-5 Details
Chemical Name: (S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl

CAS No.: 76189-56-5

Molecular Weight: 622.67

Molecular Structure: C44H32P2

Appearance: Almost white crystalline powder

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CAS 76189-56-5 Typical Properties

Items
Standard

Appearance
Almost white crystalline powder

Purity
≥98 %( HPLC )

Optical rotation
-234 ° (C = 0.3 toluene)

Melting point
241~242℃

Brand name
Fousi chemical

CAS 76189-56-5 Usage

2,2′-bis(diphenylphosphine)-1,1′-binaphthalene and its rhodium and ruthenium derivatives can be used as highly selective homogeneous catalysts for aryl ketones, β-keto esters and Reduction of α-amino ketone.
It can also be used for asymmetric hydrogenation and hydroformylation of olefins, asymmetric Heck reaction and asymmetric isomerization of allyl groups.
Ligands for palladium-catalyzed asymmetric tandem Heck reaction. This carbanion trapping process can synthesize tricyclic sesquiterpenes.
It can also be used for the asymmetric hydrogenation of α,β-unsaturated acid catalyzed by ruthenium.

CAS 76189-56-5 Packaging and Shipping
Packing: 25kg/drum
CAS 76189-56-5 Storage
Stored in cool dry ventilated place away from fire, heat, light, acids and food materials

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